Top Voted Answer
OK, to be specific you gain the power armour training perk about 3/4 through the main quest, you can get it any time after the quest "The Waters of Life" (the one where you must escort Dr. Li through the tunnels). After this quest, ask Elder Lyons about power armour training, he will agree to give permission for you to train. After this go into the main courtyard and talk to "Gunny" (the drill Sargent), who can usually be found wandering around it during the day. Ask him for training and you'll get the perk.
If you have blown up megaton you can continue the main quest by finding your way to the GNR tower (there is a metrostation NW of the main city ruins, go through that to get past all the rubble and the tower's in the north of the area). I would recommend you do this as the quest nets you a useful "Fatman" Launcher. Alternatively you can go strait to Rivet City (go onto the East side of the river and follow it south) and talk to Dr Li to instantly advance the quest.
If you're having trouble finding Rivet City then you can pick up the "Wasteland Survival Guide" quest from the NPC Moira Brown. She is normally the shopkeeper in Megaton but if you chose to nuke it then she will appear in The Underworld as a ghoul. The final part of the guide (which you will need to complete 6 quests with good rewards to complete) involves going to rivet city.
Here's a map to help you. Rivet City is at 98, The GNR tower is at 50 and the metro you need to go through to reach it is at 4C (the easiest way to get to it is to use the bridge near the Super Dupa Mart);
http://fallout.wikia.com/wiki/Fallout_3_map Bisected8 (Expert) - 10 years ago
The Citadel, just play through the main quest and you should get there yakuza281 - 10 years ago
Go to the Citadel and find elder Lyons, he will grant you permission to train for power armor as long as you have good Karma. KingsXVI - 10 years ago
After you get permission, you need to go in the center of the cidadel where all of the people are training and just talk to the guy walking around (the center) wearing power armor. redskin92 - 10 years ago
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