Enter the following codes in the regular (offline) Cheat Codes menu. A message will confirm correct code entry. All are for local split-screen multiplayer, though the Walther PPK gun can be used in single-player (press Triangle to enable/disable before starting a mission, as per the message at the bottom of the screen).
Effect Code Acute Hearing/Long-Reach Gadgets qbranch3d Moonraker Laser MK2 m00nlas3r Moonraker Suit astr0b0y Play as Baron Samedi/Jaws v00d00f1sh Play as Goldfinger/Pussy Galore au43v3r Walther PPK/Fast-Switch Gadget g3tb0nd
Contributed By: prudoff.
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You can submit a problem report for any non-working or fake code in the lists above.