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I've mentioned this a few times to different people so I figured I might as well put it here too.
Rare Materials / Weapons The higher the difficulty, the easier it is to get the rarer items. Also, the more luck you have the more often they will appear. So using Luck + accessories, hunting Luck + Fugitives, and playing on the highest difficulty all would help contribute to getting rare items / new weapons / weapon upgrades
Robes / Smooth Operator. Many people use The Last Stand to get robes and / or the Smooth Operator title / trophy (specifically with long ranged attack characters). As long as you can dodge the bomb guys, I find the Tenkai route for the Tenkai / Kingo (Siege of Karasu Castle) stage to be the easiest and fastest way of getting robes with most characters since Tenkai is really easy to perfect in a fight.
Another thing you could do is Amago's stage w/ Shimazu. OHKO to start, go to the first camp area, he reappears w/ 1 hp, hit him, get robe.
Adawg Fact #1: I'm sXe and that means I'm better than you. F.A.B Fact #2: I'm a Puro newbie and a HUGE RoH mark!