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From: Kratos1173 | #001 Q: What is the best level for grinding to 100? A: Sekigahara - Intrusion. You'll know why when you play it.
I should point out that as long as you're getting all accessories, killing Fugitives in Hero Time racks up tons of EXP. 10,000 for each Fugitive, x2 for Hero Time, multiplied by difficulty modifier. Easily Lv80 in 2 playthroughs on normal, and still getting 2 to 4 levels per stage. If you've gotten all four of a characters personal accessories and still need more EXP, Sekigahara Intrusion would be useful indeed, but let's leave that as a last resort.
From: Kratos1173 | #002 Motonari - Don't have it yet.
From the Item/Route document: "When setting traps, Motonari gains super armor and his traps will last twice as long".