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It's possible, did it the other day while streaming to some friends. The bullet sparks off the metal of the scope as it enters and exits both sides then turns his eye to goo and exits the back of his head in full bloody goodness.
Still, my best shot ever was the triple I got, shot from the top of a building down at a guy and the bullet went through his eye out the back of his neck into his friends testicle then ricochets off an enemies rifle that was laying prone behind them and goes directly into his eye. It was amazing, and I got the achy for getting a ricochet headshot from it. Win/win
I came across some Colonel giving a pep talk to a line of his men, 5 of em to be exact. Thought it'd be funny to shoot his grenade when he was walking around in front of em; not only was it the most gruesome x-ray I'd seen so far (all the stomach area organs exploded) but I also killed his men in the blast. Glorious.
XBox Live/PSN GT: Gritzy85 "Man can overcome anything except a succession of ordinary days." - Goethe