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Sakata Gintoki's equipment? Not on way of the samurai - divine appears in way of the samurai after you beat Queen's Eyes but it's still super duper rare.
That's not actually true. Divine rarity is unlocked as soon as you kill YNO in The Demon King Revealed. It drops the eight divine weapons, remember. You can start finding divine stuff after that point, including in earlier missions in WotSamurai, and definitely in Queen's Eyes on Samurai.
Eclipsing power is, at times, not only the instrument of demons, but also of gods. Lost, but not forgotten.