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There's a bright green glowing formula on the wall between the portal room and the basement to the prisoners. If you examine it you're tole "this formula feels different to the rest of this place" or something like that. But I can't figure out what it's actually for.
Edit: I found the painting of Elienai's sister right after posting this. it opens the 5th box, and there's basically nothing in it >_> (just 200 existence or some unless amount)